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Last Loaded on Web: Wednesday, October 01, 2008
Polymer Online is the online version of the Second Edition of the Encyclopedia of Polymer Science and Engineering, published by John Wiley and Sons, Inc. The database provides coverage of polymer science and engineering, including materials, methods, and the latest advances in macromolecular science. Natural and synthetic polymers, plastics, fibers, elastomers, and processing are all included in the scope of the database.
Polymer Online provides access to a wide range of chemistry subject areas including:
Polymer Online contains the full text of Wiley's Encyclopedia of Polymer Science and Engineering, 2nd edition, 17 volumes, Supplement, and cumulative index. The Encyclopedia contains approximately 600 articles (chapters) written by contributors who are experts in their fields. The articles include over 3,000 tables, 3,000 figure titles, and six million words of text.
| Dates Covered: | 2nd edition of the Encyclopedia, 1985-1989 |
|---|---|
| File Size: | 19,525 records as of January 1998 |
| Update Frequency: | Irregular (As supplements and revisions are made available) |
| ACRONYM | CATEGORY NAME |
|---|---|
| CHEMPROP | Chemical Properties |
| PLASTICS | Rubber and Plastics |
| SCITECH | Science and Technology |
|
Polymer Online is produced by John Wiley & Sons, Inc. Questions concerning file content should be directed to: 605 Third Avenue New York, NY 10158
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Copyright by John Wiley & Sons, Inc. All rights reserved. For Dialog's Redistribution and Archive Policy, enter HELP ERA online.
| DIALOG(R)File 322:Polymer Online | |
| (c) 1990 John Wiley & Sons Inc. All rts. reserv. | |
| AZ=, RT= | 311190000 Summary |
| CH= | Chapter CH=21119 |
| TY= | Type TY=211190 |
| UN= | Unit UN=211190000 |
| /TI | Chapter Title: Polyamides, Fibers |
| AU= | Author: Saunders, James H. |
| CS= | Institution: Consultant |
| SO= | Source: Encyclopedia of Polymer Science and Engineering, Second |
| Edition, Vol. 11, Pages 410-445. | |
| Number of Sections = 8 Tables = 6 Descriptors= 92 | |
| References = 152 | |
| Abstract: | |
| /AB | The history, growth, and economic importance of polyamide |
| fibers are reviewed briefly. The manufacture of nylon-6 and | |
| -6,6 is discussed with emphasis on continuous-filament fibers | |
| and yarns. Spinning, drawing, and texturing operations are | |
| described, including fiber finishes and additives. The | |
| properties of nylon-6 and -6,6 are given; dyeability is | |
| reviewed. Bicomponent and biconstituent fibers, and block and | |
| random copolymers are mentioned. Applications are outlined; | |
| growths of these markets are indicated. Vol. 11, pp. 410-445, | |
| 150 Refs. to January 1985. | |
| /SH | Section Headings: |
| Untitled (SELECT SN=21119S10 | |
| SN= | Preparation of Polyamides (SELECT SN=21119S2) |
| Raw Materials | |
| Polymerization | |
| Manufacture of Nylon-6 and -6,6 Fibers and Yarns | |
| (SELECT SN=21119S3) | |
| Spinning Continuous-filament Yarn | |
| Draw-Twisting | |
| Spin-Drawing Processes | |
| New Developments in Spinning and Drawing | |
| Texturing Processes | |
| Fine-tex Yarns | |
| Heavy-tex Yarns | |
| Heat Setting | |
| Staple Fiber | |
| (...) | |
| /TT | Tables: |
| Table 1. Physical Properties of Nylon-6 and -6,6 | |
| TN= | Continuous-filament Yarns**a (SELECT TN=21119T1) |
| Table 2. Thermal Properties of Nylon-6 and -6,6, DEGREES C**a | |
| (SELECT TN=21119T2) | |
| Table 3. Commercial Bicomponent Fibers (SELECT TN=21119T3) | |
| Table 4. Properties of Qiana Nylon Yarns (SELECT TN=21119T4) | |
| Table 5. Dimensionally Stable Experimental Nylons | |
| (SELECT TN=21119T5) | |
| Table 6. Other Experimental Nylons (SELECT TN=21119T6) | |
| /FT | Figure Titles: |
| Fig. 1. Conventional spinning apparatus. | |
| Fig. 2. Nylon-6,6 spin-draw tire-yarn apparatus. | |
| Fig. 3. Tangent modulus (DN TRIANGLE), tenacity (CIRCLE), and | |
| elongation (TRIANGLE) as a function of take-up | |
| velocity for nylon-6. To convert N/tex to gf/den, | |
| multiply by 11.33. | |
| /DE | Descriptors: |
| Adipic acid, polyamides from, #11:411 | |
| Anatase, as whitening agent, #11:423 | |
| Antistatic agents, for fibers, #11:421 | |
| Apparel, nylons for, #11:439 | |
| Aramids, definition, #11:410 | |
| Bicomponent fibers, forms, #11:434 | |
| (...) |
| DIALOG(R)File 322:Polymer Online | |
| (c) 1990 John Wiley & Sons Inc. All rts. reserv. | |
| AZ=, RT= | 211191002 Text |
| CH= | Chapter CH=21119 |
| TY= | Type TY=211191 |
| UN= | Unit UN=211191002 |
| /TI | Chapter Title: Polyamides, Fibers |
| Text continues in 211191003 | |
| /SH | Section Heading: Manufacture of Nylon-6 and -6,6 Fibers and Yarns |
| /TX | Text: |
| All polyamides other than the aromatic types, ie, aramids, are | |
| melt-spun. This process is more economical for polyamides melting | |
| below ca 280 DEGREES C than solution spinning. Thus it is preferred | |
| for nylon-6,6,nylon-6, and many others that have been studied on a | |
| smaller scale; wet spinning has been reviewed (17) (see also FIBERS, | |
| MANUFACTURE). | |
| In melt spinning, molten polymer is delivered from an extruder | |
| or a metal-grid melter (an early commercial process), or | |
| (...) |
| DIALOG(R)File 322:Polymer Online | |
| (c) 1990 John Wiley & Sons Inc. All rts. reserv. | |
| AZ=, RT= | 211192001 Table |
| CH= | Chapter CH=21119 |
| TY= | Type TY=211192 |
| UN= | Unit UN=211192001 |
| /TI | Chapter Title: Polyamides, Fibers |
| /TT | Table: Table 1. Physical Properties of Nylon-6 and-6,6 Continuous |
| filament Yarns**a | |
| Table Data: | |
| /TC, TH= | Property Normal tenacity High tenacity |
| ====================================== =============== ============= | |
| /TE, /TR, /TH | tenacity, N/tex**b 0.4-0.6 0.75-0.84 |
| -------------------------------------- --------------- ------------- | |
| wet 0.36-0.51 0.64-0.7 | |
| -------------------------------------- --------------- ------------- | |
| loop 0.40-0.49 0.57-0.69 | |
| -------------------------------------- --------------- ------------- | |
| knot 0.35-0.42 0.52-0.72 | |
| -------------------------------------- --------------- ------------- | |
| tensile strength, MPa**c 580-635 855-952 | |
| -------------------------------------- --------------- ------------- | |
| elongation at break, % | |
| -------------------------------------- --------------- ------------- | |
| conditioned 23-43 12-17 | |
| -------------------------------------- --------------- ------------- | |
| wet 28-41 14-21 | |
| -------------------------------------- --------------- ------------- | |
| tensile modulus, conditioned, N/tex**b 2.2-3.1 2.9-4.1 | |
| -------------------------------------- --------------- ------------- | |
| average toughness, N/tex**b 0.07-0.14 0.06-0.14 | |
| -------------------------------------- --------------- ------------- | |
| moisture regain at 21 DEGREES C, % | |
| -------------------------------------- --------------- ------------- | |
| 65% rh 4.5 3.3-4.5 | |
| -------------------------------------- --------------- ------------- | |
| 95% rh 7.1-7.8 7.8 | |
| -------------------------------------- --------------- ------------- | |
| /TF | Table Footnotes: |
| **a Conditioned at 65% rh and 21 DEGREES C. | |
| **b To convert N/tex to gf/den, multiply by 11.33. | |
| **c To convert MPa to psi, multiply by 145. |
| DIALOG(R)File 322:Polymer Online | |
| (c) 1990 John Wiley & Sons Inc. All rts. reserv. | |
| AZ=, RT= | 211193000 Bibliography |
| CH= | Chapter CH=21119 |
| TY= | Type TY=211193 |
| UN= | Unit UN=211193000 |
| /TI | Chapter Title: Polyamides, Fibers |
| Bibl. continues in 211193001 | |
| References = 152 | |
| Patent Nos: | |
| PN= | US 2071250; US 2071253; US 2130523; US 2130948; US 2783609; |
| US 2803105; US 2803108; US 2803109; US 2852906; US 2862879; | |
| US 2869967 ; US 2884756; US 2919534; US 2933771; US 2942402; | |
| US 2958112; US 3005251; US 3021588; US 3024516; US 3024517; | |
| US 3025584; US 3031734; US 3101521; US 3137911; US 3140525; | |
| US 3164882; US 3311691; US 3994121; US 4093147; US 4181697; | |
| US 4238439 | |
| References: | |
| /BR | 1. S. Gabriel and T. A. Maas, Ber. 32, 1266 (1899). |
| 2. H. Mark and G. S. Whitby, eds., ''Collected Papers of Wallace | |
| Hume Carothers on High Polymeric Substances,'' High Polymers, | |
| Vol. I Interscience Publishers, New York, 1940. | |
| 3. E. K. Bolton, Ind. Eng. Chem. 34, 53 (1942); reprinted in | |
| Chem. Technol. 6, 459 (1976). | |
| 4. C. S. Marvel and C. E. Carraher, Jr., Chem. Technol. 14, 716 | |
| 1984. | |
| 5. O. L. Shealy, Fiber Prod. 12(2), 32 (1984) | |
| (...) | |
| General References: | |
| ''Polyamide Fibers'' in EPST 1st ed., Vol. 10, pp. 347-460, by | |
| O. E. Snider and R. J. Richardson, Allied Chemical | |
| Corporation. | |
| Refs. 24 and 145 are good general references. | |
| H. F. Mark, S. M. Atlas, and E. Cernia, eds., Man-Made Fibers: | |
| Science and Technology, 3 Vols., Wiley-Interscience, New | |
| York, 1967-1968. | |
| E. M. Hicks, Jr. and co-workers, Text. Prog. 3, 1 (1971). | |
| A. J. Hughes and J. E. McIntrye, Text. Prog. 8, 18 (1976). | |
| Z. K. Walczak, Formation of Synthetic Fibers, Gordon & Breach | |
| Science Publishers, Inc., New York, 1977. | |
| J. H. Saunders, ''Polyamide Fibers'' in M. Grayson, ed., | |
| Encyclopedia of Chemical Technology, 3rd ed., Vol. 18, | |
| Wiley-Interscience, New York, 1982, p. 373. |
| SEARCH SUFFIX |
DISPLAY CODE |
FIELD NAME |
INDEXING |
SELECT EXAMPLES |
|---|---|---|---|---|
| None | None | All Basic Index Fields1 | Word | S BICONSTITUENT(W)FIBERS |
| /AB | AB | Abstract2 | Word | S BICONSTITUENT(W)FIBERS/AB |
| /BR | BR | Bibliography Reference3 | Word | S CHEM(W)TECHNOL/BR |
| /DE | DE | Descriptor2 | Word & Phrase |
S WHITENING(W)AGENT/DE S ADIPIC ACID?/DE |
| /FT | FT | Figure Title2 | Word | S SPINNING(W)APPARATUS/FT |
| /SH | SH | Section Heading2,4 | Word & Phrase |
S PREPARATION(1W)POLYAMIDES/SH S STAPLE FIBER/SH |
| /TC | TC | Table Column Heading5 | Word | S NORMAL(W)TENACITY/TC |
| /TE | TE | Table Entry5,6 | Word | S TENSILE(W)STRENGTH/TE |
| /TF | TF | Table Footnote5 | Word | S 21(W)DEGREES(W)C/TF |
| /TH | TH | Table Heading5,7 | Word | S TENSILE(W)MODULUS/TH |
| /TI | TI | Chapter Title | Word & Phrase |
S POLYAMIDES(W)FIBERS/TI S POLYAMIDES, FIBERS/TI |
| /TR | TR | Table Row Heading5 | Word | S AVERAGE(W)TOUGHNESS/TR |
| /TT | TT | Table Title2,5 | Word | S NYLON(W)6/TT |
| /TX | TX | Text4 | Word | S MELT(W)SPUN/TX |
1 All words are indexed, including the standard Dialog stop words.
3 Present in Bibliography records.
6 Table entries are searched and displayed by Row Heading (/TR), Column Heading (/TC), and corresponding data.
7 Retrieves a term as either a Column Heading (/TC) or a Row Heading (/TR).
| SEARCH PREFIX |
DISPLAY CODE |
FIELD NAME |
INDEXING |
SELECT EXAMPLES |
|---|---|---|---|---|
| AU= | AU | Author2 | Phrase | S AU=SAUNDERS, J? |
| AZ= | AZ | DIALOG Accession Number | Phrase | S AZ=211190000 |
| CH= | CH | Chapter Number | Phrase | S CH=21119 |
| CN= | None | Citation Number8,9 | Phrase | S CN=21119R17 |
| CS= | CS | Corporate Source2 | Word & Phrase |
S CS=CONSULTANT S CS=INDIAN INSTITUTE? |
| None | ND | Number of Descriptors2 | ||
| None | NR | Number of References2 | ||
| None | NS | Number of Sections2 | ||
| None | NT | Number of Tables2 | ||
| PN= | PN | Patent Number3 | Phrase | S PN=US S PN=US 2071250 |
| RT= | RT | Record Type | Phrase | S RT=SUMMARY |
| SN= | SN | Section Number9 | Phrase | S SN=21119S2 |
| SO= | SO | EPS&E Source2 | Word | S SO=(VOL(W)11) |
| None | TA | Table Data with greater than (>) sign indicating new rows10 | ||
| None | TB | Table Data with dashes (--) indicating new rows10 | ||
| None | TG | Table Data by row with semicolons separating data10 | ||
| TN= | TN | Table Number9 | Phrase | S TN=21119T1 |
| TY= | TY | Record Type Number9 | Phrase | S TY=211190 |
| UN= | UN | Unit Number9 | Phrase | S UN=211190000 |
8 References are displayed in groups of ten when retrieved with CN=. For the complete Bibliography record use CH= and /BIBL.
9 Search fields used to quickly retrieve a specific item(s).
| Sets and items may be restricted using Basic Index suffixes, i.e., /AB, /BR, /DE, /FT, /SH, /TC, /TE, /TF, /TH, /TI, /TR, /TT and /TX. | ||
| SUFFIX | FIELD NAME | EXAMPLES |
|---|---|---|
| /BIBL | Bibliography Records | S S2/BIBL |
| /SUM | Summary Records | S S3/SUM |
| /TABLE | Table Records | S S2/TABLE |
| /TEXT | Text Records | S S4/TEXT |
| RANK FIELDS | EXAMPLES |
|---|---|
| All phrase- and numeric-indexed fields in the Additional Indexes can be ranked. Other RANK codes include: DE | RANK DE RANK CH S4 |
| MAP FIELDS | EXAMPLES |
|---|---|
| CH, PN, TY, UN | MAP CH TEMP S3/1 |
| DISPLAY TAG | RECORD CONTENT |
|---|---|
| Display codes listed in the Search Options tables can be used to customize output. | TYPE S3/TI,AU,CS,SO/ALL |
| NO. |
DIALOGWEB FORMAT |
RECORD CONTENT |
|---|---|---|
| 1 | -- | DIALOG Accession Number |
| 2 | -- | Record Type, Chapter Number, Record Type Number, Unit Number, Chapter Title, and Number of References |
| 3 | Medium | Same as Format 2 |
| 4 | -- | Same as Format 2 |
| 5 | -- | Full Record |
| 6 | -- | Same as Format 2 except Number of References |
| 7 | Long | Full Record |
| 8 | Short | Same as Format 2 plus Patent Numbers |
| 9 | Full | Full Record |
| K | -- | KWIC (Key Word In Context) displays a window of text; may be used alone or with other formats |
| SUMMARY RECORDS | ||
| 2 | -- | Record Type, Chapter Number, Record Type Number, Unit Number, Chapter Title, Author, Corporate Source, Source, Number of Sections, Number of Tables, Number of Descriptors, Number of References, Abstract, Section Headings, Table Title, and Figure Title |
| 3 | Medium | Same as Format 2 except Abstract, Section Headings, Table Titles, and Figure Titles |
| 4 | -- | Same as Format 2 |
| 5 | -- | Full Record |
| 6 | -- | Record Type, Chapter Number, Record Type Number, Unit Number, and Chapter Title |
| 7 | Long | Full Record |
| 8 | Short | Same as Format 6 plus Descriptors |
| 9 | Full | Full Record |
| K | -- | KWIC (Key Word In Context) displays a window of text; may be used alone or with other formats |
| TABLE RECORDS | ||
| 2 | -- | Record Type, Chapter Number, Record Type Number, Unit Number, Chapter Title, Table Title, Column Headings, Row Headings, and Table Footnotes |
| 3 | Medium | Same as Format 2 except Column Headings, Row Headings and Table Footnotes |
| 4 | -- | Same as Format 2 |
| 5 | -- | Full Record (full table data displayed with >'s indicating each new line) |
| 6 | -- | Record Type, Chapter Number, Record Type Number, Unit Number, and Chapter Title |
| 7 | Long | Full Record (full table data displayed with dashes (---) between each new line |
| 8 | Short | Same as Format 6 plus Table Title |
| 9 | Full | Full Record (full table data displayed with >'s |
| K | -- | KWIC (Key Word In Context) displays a window of text; may be used alone or with other formats |
| TEXT RECORDS | ||
| 2 | -- | Record Type, Chapter Number, Record Type Number, Unit Number, Chapter Title, and Section Heading |
| 3 | Medium | Same as Format 2 |
| 4 | -- | Same as Format 2 |
| 5 | -- | Full Record (complete text of a section) |
| 6 | -- | Same as Format 2 except Section Heading |
| 7 | Long | Full Record (complete text of a section) |
| 8 | Short | Record Type, Chapter Number, Record Type Number, Unit Number, Chapter Title, and Section Heading |
| 9 | Full | Full Record (complete text of a section) |
| K | -- | KWIC (Key Word In Context) displays a window of text; may be used alone or with other formats |
| FIELD NAME | EXAMPLES | ||
|---|---|---|---|
| If the accession number of a specific record is known, it can be used to display the record directly. | TYPE 211193000/5 DISPLAY 211191002/2 PRINT 211192001/7 |
||
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